Bulletin of the Chemical Society of Japan

The reaction of copper (I) methyltrialkylborates with allylic halides or 2-propynylic halides.

N Miyaura, M Itoh, A Suzuki

Index: Miyaura,N. et al. Bulletin of the Chemical Society of Japan, 1977 , vol. 50, p. 2199 - 2200

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Citation Number: 27

Abstract

The reactions between copper (I) methyltrialkylborates (readily obtainable from organoboranes) and allylic halides or 2-propynylic halides were found to give corresponding alkylation products. These reactions provide novel synthetic routes to 1- alkenes or 1, 2-alkadienes from organoboranes.