Medium Effects on Zwitterionic??Biradicaloid Intermediates from Two Phenyl?簋螃窿?oxoamides. Irradiations in Fluid and Solid Protic Media, Neat Solid Phases, and the …

CA Chesta, M George, C Luo…

Index: Chesta, Carlos A.; George, Mathew; Luo, Chuping; Weiss, Richard G. Photochemistry and Photobiology, 2007 , vol. 83, # 3 p. 570 - 583

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Abstract

Abstract The photochemical processes of two N, N-dialkyl phenyl-α-oxoamides, N, N- diisopropyl phenyl-α-oxoamide (1) and N, N-dibenzyl phenyl-α-oxoamide (2), are investigated at different temperatures in methanol and ethylene glycol (to probe the influences of H-bonding and viscosity), in the solid phase of d-sorbitol at room temperature (to compare with the results in the liquid alcohols and to assess the influence of a poorly ...