Controlled radical polymerization of styrene??based models of the active site of the [FeFe]??hydrogenase

…, C Pietsch, US Schubert, W Weigand

Index: Heine, Daniel; Pietsch, Christian; Schubert, Ulrich S.; Weigand, Wolfgang Journal of Polymer Science, Part A: Polymer Chemistry, 2013 , vol. 51, # 10 p. 2171 - 2180

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Citation Number: 7

Abstract

Abstract Within this study, we report on the first controlled radical polymerization of styrene- based models of the active site of the [FeFe]-hydrogenase. Three different model complexes based on styrene were prepared including propanedithiolato-bridged, 2- azapropanedithiolato-bridged, and bifunctional styrene iron complex. These model complexes were copolymerized with styrene using free radical and the reversible addition ...