A novel clathrate design: selective inclusion of uncharged molecules via the binaphthyl hinge and appended coordinating groups. X-ray crystal structures and binding …

…, I Csoregh, B Stensland, M Czugler

Index: Weber, Edwin; Csoregh, Ingeborg; Stensland, Brigitta; Czugler, Matyas Journal of the American Chemical Society, 1984 , vol. 106, # 11 p. 3297 - 3306

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Citation Number: 129

Abstract

Abstract: l, l'-Binaphthyl-2, 2'-dicarboxylic acid (1) is demonstrated as a novel type of clathrate host whose main mode of action is derived from a combination of the steric barrier and the coordinative interaction principle which constitutes the new “coordinatoclathrate” strategy. Inclusion properties of the crystal lattice of 1 are revealed for a variety of uncharged organic guest molecules (30 examples), ranging from OH-, to NH-, to CH-acidic ...