The Journal of Organic Chemistry

Improved Preparations of 3-Chloro-2-(chloromethyl)-1-propene and 1, 1-Dibromo-2, 2-bis (chloromethyl) cyclopropane: Intermediates in the Synthesis of [1.1. 1] …

KM Lynch, WP Dailey

Index: Lynch, Kathleen Mondanaro; Dailey, William P. Journal of Organic Chemistry, 1995 , vol. 60, # 14 p. 4666 - 4668

Full Text: HTML

Citation Number: 41

Abstract

In our hands their new procedure provided a more convenient workup than previous ones, 1s2 but no significant increase in yield. We were unable to approach their reported yields (70%) even with several attempts on the same scale. This has prompted us to report our modified procedures that allow the preparation of large quantities of 2 and 3 in good yields.