Organometallics

Rhodium Cyclopentyl Phosphine Complexes of Wide-Bite-Angle Ligands DPEphos and Xantphos

R Dallanegra, AB Chaplin, AS Weller

Index: Dallanegra, Romaeo; Pilgrim, Ben S.; Chaplin, Adrian B.; Donohoe, Timothy J.; Weller, Andrew S. Dalton Transactions, 2011 , vol. 40, # 25 p. 6626 - 6628

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Citation Number: 22

Abstract

Rh (I) and Rh (III) complexes of tricyclopentylphosphine (PCyp3), or its dehydrogenated variant PCyp2 (η2-C5H7), partnered with wide-bite-angle chelating diphosphine ligands DPEphos and Xantphos have been prepared and characterized in solution and the solid