Chelate polymers. VI. New copolymers of the some siloxane containing bis (2, 4-dihydroxybenzaldehyd-imine) Me 2+ with bis (p-carboxyphenyl) diphenylsilane

…, M Marcu, A Vlad, GI Rusu, M Avadanei

Index: Cazacu, Maria; Marcu, Mihai; Vlad, Angelica; Rusu, Gheorghe I.; Avadanei, Mihaela Journal of Organometallic Chemistry, 2004 , vol. 689, # 19 p. 3005 - 3011

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Citation Number: 54

Abstract

New high complex polymeric structures containing metal chelate sequences alternating, through esteric bridges, with silane units were obtained. The azomethine of 2, 4- dihydroxybenzaldehyde with 1, 3-bis (aminopropyl) tetramethyldisiloxane has been synthesized and in situ complexed with copper (II), nickel (II), cobalt (II) and cadmium (II). The obtained bis-phenolic chelates were covalently inserted in polymeric linear structures ...