The Journal of Organic Chemistry

Dephosphonylation of β-Carbonyl Phosphonates

SY Lee, CW Lee, DY Oh

Index: Jang, Won Bum; Shin, Won Suk; Hong, Jong Eun; Lee, Shi Yong; Oh, Dong Young Synthetic Communications, 1997 , vol. 27, # 19 p. 3333 - 3339

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Citation Number: 16

Abstract

A new methodology has been developed for the PC bond cleavage of β-carbonyl phosphonates. The α, α-disubstituted β-keto phosphonates and the α-carbamoyl phosphonates have been shown to undergo dephosphonylation by reaction of their lithium