Tetrahedron

Organic photochemistry—II: Photochemical reaction of 5-phenyltropolone and its methyl ether

T Mukai, T Miyashi

Index: Mukai,T.; Miyashi,T. Tetrahedron, 1967 , vol. 23, p. 1613 - 1620

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Citation Number: 9

Abstract

Photochemistry of 5-phenyltropolone methyl ether (I) has been compared with that of colchicine and isocolchicine. Irradiation of I in methanol using high pressure mercury lamp afforded 3-methoxy-6-phenyl-Δ3, 6-bicyclo [3.2. 0] heptadiene-2-one (II). This is the first example giving type C photo-valence isomerization in the photo-reaction of a simple troponoid system. Photochemistry of 5-phenyltropolone (IX) was also studied, where both ...

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John Howland Rowe Bibliography

[Doering; Knox Journal of the American Chemical Society, 1953 , vol. 75, p. 297,300]

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[Banwell, Martin G.; Collis, Maree P.; Crisp, Geoffrey T.; Lambert, John N.; Reum, Monica E.; Scoble, Judith A. Journal of the Chemical Society, Chemical Communications, 1989 , # 10 p. 616 - 617]