Photocatalysis of oligo (p-phenylenes): photoreductive production of hydrogen and ethanol in aqueous triethylamine

S Matsuoka, H Fujii, T Yamada, C Pac…

Index: Matsuoka, Shinjiro; Fujii, Hiroyuki; Yamada, Taisuke; Pac, Chyongjin; Ishida, Akito; et al. Journal of Physical Chemistry, 1991 , vol. 95, # 15 p. 5802 - 5808

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Citation Number: 52

Abstract

Conclusion The conformation and the stabilization energy of pyrenyl dimer radical cation were studied for three intramolecular dipyrenyl propane. 1 Py 1 w+ and 2 P y 2 w+ form full- overlap dimer radical cations which have a CR band peak at ca. 1600 nm. The overlap structure by only two benzene rings of 1Py2Py'+ decreased the stabilization energy more than 2.4 kcal mol-'from that of the full-overlap type. The dimer radical cation of ...