Mechanistic studies of the tellurium (II)/tellurium (IV) redox cycle in thiol peroxidase-like reactions of diorganotellurides in methanol

Y You, K Ahsan, MR Detty

Index: Engman, Lars; Persson, Joachim; Andersson, Carl M.; Berglund, Mats Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1992 , # 8 p. 1309 - 1313

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Citation Number: 82

Abstract

... Journal of the ... 2003, 125 (16), pp 4918–4927. DOI: 10.1021/ja029590m. Publication Date (Web): March 27, 2003. Copyright © 2003 American Chemical Society. ... tellurane 1. The rate of addition of water, k 1 , to the telluroxide as shown in Scheme 3 is on the order of 10 3 M - 1 s ...