Synthesis of the first optically pure, fluorinated inositol 1, 4, 5-trisphosphate of myo-inositol. Stereochemistry and its effect on calcium (2+) release in Swiss 3T3 cells

…, AH Fauq, IA Aksoy, MJ Seewald, G Powis

Index: Kozikowski; Fauq; Aksoy; Seewald; Powis Journal of the American Chemical Society, 1990 , vol. 112, # 20 p. 7403 - 7404

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Citation Number: 73

Abstract

A few examples are also known for niobium: viz. [Nb6H&]"+ (n = 2 or 3) containing H as the centering element.1° Up till now, it has been considered that these centered cluster species are stabilized by addition of electrons from the valence orbitals of the centering element to the bonding metal-metal orbitals of the cluster unit.' Thus, with few exceptions, these clusters exist only when the centering atom is present. However, in the case of MO@(OEt)l8, which has 16 ...