Kinetics and mechanism of the thermal rearrangement of [1.1. 1] propellane

O Jarosch, R Walsh, G Szeimies

Index: Hopf, Henning; Wachholz, Gerhard; Walsh, Robin Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986 , p. 1103 - 1106

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Citation Number: 13

Abstract

The kinetics of the thermal rearrangement of [1.1. 1] propellane (1) have been investigated by gas-phase pyrolysis in a stationary system. The unimolecular reaction leads to dimethylenecyclopropane (2) and its thermal isomerization product