Journal of Molecular Spectroscopy

The A 3 Π (1)→ X 1 Σ (0+) emission spectrum of iodine monofluoride: Analyses of the vibrational and rotational structure

BD McFeeters, EA Walters, PJ Wolf

Index: McFeeters, Brian D.; Walters, Edward A.; Wolf, Paul J. Journal of Molecular Spectroscopy, 1989 , vol. 135, p. 1 - 21

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Citation Number: 4

Abstract

Abstract Iodine monofluoride A 3 Π (1)→ X 1 Σ (0+) emission has been observed in the reaction of I 2 with F 2 at temperatures ranging from 300 to 800 K. Two previously unreported v′ progressions are identified, and vibrational molecular constants are reported for the IF 3 Π (1) state using bandheads in progressions based on 0≤ v′≤ 15 and 0≤ v ″≤ 5. The rotational structure has also been recorded and analyzed for nine vibrational ...