Liebigs Annalen der Chemie

Synthesis of sphingosine relatives, VII. Synthesis of anti??ulcerogenic cerebrosides isolated from Tetragonia tetragonoides

K Mori, T Kinsho

Index: Mori, Kenji; Kinsho, Takeshi Liebigs Annalen der Chemie, 1988 , p. 807 - 814

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Citation Number: 14

Abstract

Tbc synthesis of (3,3R,4E.8E.Z'R )-1-O~~D-glucopyranosyl)-N- (2'-hydroxyhexadecanoyl)-4,8 -sphingadienine (1 a) and its (82) isomer 1 b was accomplished by employing (R )-Zaminohexade- canoic acid. D-glUCOSe, and (S)-scnnc as chiral sources. ... In 1983, Yamazaki et al. isolated anti-ulcerogenic prin- ciples from an oriental drug - Tetragoniae Herba (Bankyoo - the whole plant of Tetragonia tetragonoides)*). Among these principles, compound B1 ( ...