Charge reversal of electrophilic π-allylpalladium intermediates; carbonyl allylation by allylic acetates with PdCl 2 (PhCN) 2–SnCl 2

Y Masuyama, R Hayashi, K Otake…

Index: Masuyama, Yoshiro; Hayashi, Ryoji; Otake, Kiyotaka; Kurusu, Yasuhiko Journal of the Chemical Society, Chemical Communications, 1988 , # 1 p. 44 - 45

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Citation Number: 25

Abstract

Carbonyl allylation by stable allylic acetates with Pdo-SnCI2 occurred regio-, chemo-, and diastereoselectively to afford the corresponding homoallylic alcohols. ... The addition reaction of allylic organometallic reagents with aldehydes is one of the most synthetically useful methods for ... Published on 01 January 1988. Downloaded by google on 30/03/2016 18:41:35. ... View Article Online / Journal Homepage / Table of Contents for this issue ... Scheme 2. Reagents and conditions: i, ...