Kinetics of the dichloromethyl and chloromethyl association reactions with molecular oxygen between 298 and 448 K and from 1 to 760 Torr of total pressure

…, R Lesclaux, JT Niiranen, D Gutman

Index: Fenter, Frederick F.; Lightfoot, Phillip D.; Caralp, Francoise; Lesclaux, Robert; Niiranen, Jukka T.; Gutman, David Journal of Physical Chemistry, 1993 , vol. 97, # 18 p. 4695 - 4703

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Citation Number: 20

Abstract

The rate constants for the recombination reactions between molecular oxygen and the halogenated methyl radicals CHC12 and CH2Cl were determined over the pressure range of 1 to 760 Torr in nitrogen as a function of temperature. The CHClz+ 0 2 reaction (1) was studied over the temperature range 298< T/K< 383 and the CHlCl reaction (2) over the range 298< T/K< 448. The large range in pressure was attained by using two ...