Tetrahedron letters

Fluorination of α, α-dichlorosulfides: access to gem-difluorothioethers as useful building blocks

…, C Guérin, L Lemoucheux, T Lequeux, JC Pommelet

Index: Gouault, Sonia; Guerin, Cecile; Lemoucheux, Laurent; Lequeux, Thierry; Pommelet, Jean-Claude Tetrahedron Letters, 2003 , vol. 44, # 27 p. 5061 - 5064

Full Text: HTML

Citation Number: 12

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The synthesis of alkylsulfanyldifluoro-acetate and ketones by the Halex reaction is described. The remarkable reactivity of thiodifluoroacetate derivatives opened rapid access for the preparation of useful building blocks such as gem-difluoroketones and amides.

~72%

Fluorination of α-phenylsulfanyl esters using difluoroiodoto...

[Motherwell, William B.; Greaney, Michael F.; Tocher, Derek A. Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 24 p. 2809 - 2815]

Novel Synthesis of Difluoromethyl??Containing 1, 4??Disubsti...

[Zhang, Jian; Wu, Jingjing; Shen, Li; Jin, Guanyi; Cao, Song Advanced Synthesis and Catalysis, 2011 , vol. 353, # 4 p. 580 - 584]

Highly efficient and selective electrochemical fluorination ...

[Sunaga, Takeshi; Atobe, Mahito; Inagi, Shinsuke; Fuchigami, Toshio Chemical Communications, 2009 , # 8 p. 956 - 958]

Synthesis and optical activity of difluoro (organylsulfinyl)...

[Matsnev, Andrej V.; Kondratenko, Nataliya V.; Yagupolskii, Yurii L.; Yagupolskii, Lev M. Tetrahedron Letters, 2002 , vol. 43, # 16 p. 2949 - 2952]