Synthesis and reactions of alkynyl oligosilanes

C Mechtler, M Zirngast, J Baumgartner…

Index: Mechtler, Christian; Zirngast, Michaela; Baumgartner, Judith; Marschner, Christoph European Journal of Inorganic Chemistry, 2004 , # 16 p. 3254 - 3261

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Citation Number: 5

Abstract

Abstract Synthesis, properties, and reactions of various alkynyl oligosilanes, and their potassium derivatives are described. A series of tris (trimethylsilyl) silylalkynes have been prepared. Their reaction with potassium tert-butoxide leads to the corresponding potassium derivatives, which can be subjected to further derivatization. X-ray structures of three oligosilylalkynes are reported.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, ...