ARKIVOC

Addition of C-nucleophiles to 5-phenylpyrimidin-2 (1H)-ones and 6-phenyl-1, 2, 4-triazin-3 (2H)-one

…, TA Tseitler, GV Zyryanov, VL Rusinov, ON Chupakhin

Index: Egorov, Ilya N.; Tseitler, Tatyana A.; Zyryanov, Grigory V.; Rusinov, Vladimir L.; Chupakhin, Oleg N. Arkivoc, 2011 , vol. 2011, # 10 p. 312 - 323

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Abstract

Abstract Addition reactions of C-nucleophiles to the C= N bond of 5-phenyl-and 1-methyl-5- phenylpyrimidin-2 (1H)-ones 1a, b and 6-phenyl-1, 2, 4-triazin-3 (2H)-one 2 were investigated. 1a, b and 2 furnished addition products with indoles; 1a also added N- methylpyrrole. Only 2 added thiophene and methyl ketones, and reacted with alkyl halides and acetone forming products resulting both from alkylation and from addition of acetone ...