Tetrahedron letters

Carbon-carbon bond formation by intermolecular radical reaction. Sml 2-promoted carbonyl-alkyne reductive coupling

J Inanaga, J Katsuki, O Ujikawa, M Yamaguchi

Index: Inanaga, Junji; Katsuki, Junko; Ujikawa, Osamu; Yamaguchi, Masaru Tetrahedron Letters, 1991 , vol. 32, # 37 p. 4921 - 4924

Full Text: HTML

Citation Number: 32

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... An efficient intermolecular carbonyl-alkyne reductive coupling reaction was realized for the first time by using the system, Sml 2 -HMPA-hydrogen donor, to give the corresponding allylic alcohols in good yields. ... For intermolecular addition of alkyl radicals to alkynes, see reference 1.