Tetrahedron

1, 3, 2, 4-Diazadiphosphetidines as new P–N ligands for palladium-catalyzed Heck reaction in water

…, H Firouzabadi, A Tarassoli, M Fereidoonnezhad

Index: Iranpoor, Nasser; Firouzabadi, Habib; Tarassoli, Abbas; Fereidoonnezhad, Masood Tetrahedron, 2010 , vol. 66, # 13 p. 2415 - 2421

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Citation Number: 61

Abstract

1, 3, 2, 4-Diazadiphosphetidine-based phosphazane class have been used as a new generation of heterogeneous bidentate P (III) ligands containing nitrogen for base-free Pd (II) catalyzed C–C bond formation through Heck coupling reaction of aryl iodides, bromides and chlorides in water with styrene, n-butyl acrylate, 1-octene, and cyclohexene. The reactions occur heterogeneously in water and homogenously or partially heterogeneously ...