Organic photochemistry. 63. Photolytic cleavage of remote functional groups in polyfunctional molecules. Photolysis of exo-and endo-benzobicyclo [2.2. 2] octen-2-yl …

…, K Muthuramu, G Pandey, D Severance…

Index: Morrison, Harry; Muthuramu, Kayambu; Pandey, Genesh; Severance, Daniel; Bigot, Bernard Journal of Organic Chemistry, 1986 , vol. 51, # 17 p. 3358 - 3363

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Citation Number: 13

Abstract

Results A. Photochemistry of exo-Benzobicyclo [2.2. 2] octen-2-yl Chloride (exo-BBCl). Synthesis. The title compound was prepared by the reaction sequence given in eq 2.6 The exo and endo isomers are formed in a 5545 ratio and were separated by preparative GLC. The'H NMR spectra of exo-BBC1 has been reported.'endo-BBCl 8x0-BBCl