Chemistry letters

Synthesis and Helical Structure of Oligo (quinoline-2, 3-diyl) s

M Suginome, H Noguchi, M Murakami

Index: Suginome, Michinori; Noguchi, Hiroyoshi; Murakami, Masahiro Chemistry Letters, 2007 , vol. 36, # 8 p. 1036 - 1037

Full Text: HTML

Citation Number: 11

Abstract

Oligo (quinoline-2, 3-diyl) s having a terminal bromo group were synthesized by the Suzuki– Miyaura coupling of 5, 8-disubstituted 2-bromoquinolin-3-ylboronic acid derivatives, and their helical structures were elucidated by a single-crystal X-ray analysis of the hexamer, UV measurements, and induction of a non-racemic helical sense by introduction of a chiral end group.