Palladium (0)??Catalyzed Cross??Couplings of 2??Bromophosphinine

N Kostenko, C Ericsson, M Engqvist…

Index: Kostenko, Nataliya; Ericsson, Cecilia; Engqvist, Magnus; Gonzalez, Susana Villa; Bayer, Annette European Journal of Organic Chemistry, 2013 , # 22 p. 4756 - 4759

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Citation Number: 3

Abstract

Abstract A new Negishi-type cross-coupling of 2-bromophosphinine has been developed. The new method expands the scope of palladium-catalyzed couplings to monobromophosphinines, which have been considered as poor substrates so far. Moreover, aryl-, alkenyl-, and alkynylzinc bromides were found to be effective coupling partners.