The Journal of Organic Chemistry

Symmetrical Tricyanobenzenes

CD Weis

Index: Weis,C.D. Journal of Organic Chemistry, 1962 , vol. 27, p. 2964 - 2965

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Citation Number: 11

Abstract

The cumbersome preparation of symmetrical tricyanotrimethylbenzene (I) (tricyanomesitylene) by a stepwise introduction of three cyano groups has been reported.' We deemed it of interest to attempt a more facile synthesis of this type of compound. The Rosenmund-von Braun reaction generally proceeds well with halogen compounds bearing the halogen atoms on nonadjacent carbon atoms. The method is satisfactory even under ...