Organic letters

Indium (III) Halide-Catalyzed UV-Irradiated Radical Coupling of Iodomethylphosphorus Compounds with Various Organostannanes

I Suzuki, K Kiyokawa, M Yasuda, A Baba

Index: Suzuki, Itaru; Kiyokawa, Kensuke; Yasuda, Makoto; Baba, Akio Organic Letters, 2013 , vol. 15, # 7 p. 1728 - 1731

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Citation Number: 4

Abstract

The first catalytic radical coupling of iodomethylphosphorus compounds was accomplished with allyl-, alkenyl-, and allenylstannanes under UV irradiation in the presence of an indium (III) halide catalyst, for which a transmetalated allylic indium species was confirmed to be an active radical species.