Ligand-elaboration as a strategy for engendering structural diversity in porous metal–organic framework compounds

T Gadzikwa, BS Zeng, JT Hupp…

Index: Gadzikwa, Tendai; Zeng, Bi-Shun; Hupp, Joseph T.; Nguyen, SonBinh T. Chemical Communications, 2008 , # 31 p. 3672 - 3674

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Citation Number: 56

Abstract

A series of 4, 4′-ethynylenedibenzoic acids were synthesized and used in the construction of Zn-based, mixed-ligand metal–organic frameworks; through variation of functionality in the 3-and 3′-positions of these linkers, a collection of MOFs with differing connectivities and varying levels of interpenetration was obtained.

~98%

Synthesis, optical properties, crystal structures and phase ...

[Fasina, Tolulope M.; Collings, Jonathan C.; Burke, Jacqueline M.; Batsanov, Andrei S.; Ward, Richard M.; Albesa-Jove, David; Porres, Laurent; Beeby, Andrew; Howard, Judith A. K.; Scott, Andrew J.; Clegg, William; Watt, Stephen W.; Viney, Christopher; Marder, Todd B. Journal of Materials Chemistry, 2005 , vol. 15, # 6 p. 690 - 697]