Synthesis of the monoterpenoid esters cypellocarpin C and cuniloside B and evidence for their widespread occurrence in Eucalyptus

…, B Cao, AM Heskes, JQD Goodger, IE Woodrow…

Index: Hakki, Zalihe; Cao, Benjamin; Heskes, Allison M.; Goodger, Jason Q.D.; Woodrow, Ian E.; Williams, Spencer J. Carbohydrate Research, 2010 , vol. 345, # 14 p. 2079 - 2084

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Citation Number: 21

Abstract

Short syntheses of cuniloside B and cypellocarpin C,(+)-(R)-oleuropeic acid-containing carbohydrates, are reported. Also disclosed are syntheses of the noreugenin glycosides, undulatoside A and corymbosins K1 and K2. Leaf extracts of 28 diverse eucalypts revealed cuniloside B to be present in all, and cypellocarpin C to be present in most, of the species examined. The widespread occurrence of these carbohydrate monoterpenoid esters ...