One-pot Claisen rearrangement with N-butyl vinyl ether

H Tokuyama, T Makido, T Ueda…

Index: Tokuyama, Hidetoshi; Makido, Takaki; Ueda, Toshihiro; Fukuyama, Tohru Synthetic Communications, 2002 , vol. 32, # 6 p. 869 - 873

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Citation Number: 5

Abstract

ABSTRACT A protocol for one-pot Claisen rearrangement with n-butyl vinyl ether is described. Upon heating allylic alcohols with excess n-butyl vinyl ether with catalytic amount of Hg (OAc) 2 and NaOAc, Claisen rearrangement takes place through in situ formation of the requisite allyl vinyl ether.

~51%

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