Sažetak Solvolysis rates, alpha and beta deuterium isotope rate effects and product yields have been determined for some 1-(1-adamantyl) propyl sulfonate esters, 4, in some ethanol- water, trifluoroethanol-water and hexafluoroisopropyl alcohol-water mixtures. For comparison, similar measurements have been made for solvolysis of 2, 2-dimethyl-3-pentyl sulfonates, 5. For the esters 5, the alpha-đ and beta-c? 2 effects vary little with solvent in ...