Croatica chemica acta

The Mechanism of Solvolysis of 2, 2-Dimethyl-3-pentyl and 1-(1-Adamantyl) propyl Sulfonates

VJ Shiner Jr, TE Neumann, BB Basinger

Index: Shiner Jr., Vernon J.; Neumann, Thomas E.; Basinger, Bradley B. Croatica Chemica Acta, 1996 , vol. 69, # 4 p. 1405 - 1420

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Citation Number: 7

Abstract

Sažetak Solvolysis rates, alpha and beta deuterium isotope rate effects and product yields have been determined for some 1-(1-adamantyl) propyl sulfonate esters, 4, in some ethanol- water, trifluoroethanol-water and hexafluoroisopropyl alcohol-water mixtures. For comparison, similar measurements have been made for solvolysis of 2, 2-dimethyl-3-pentyl sulfonates, 5. For the esters 5, the alpha-đ and beta-c? 2 effects vary little with solvent in ...