Infrared spectrum of the primary ozonide of ethylene in solid xenon

CK Kohlmiller, L Andrews

Index: Kohlmiller, Christopher K.; Andrews, Lester Journal of the American Chemical Society, 1981 , vol. 103, # 10 p. 2578 - 2583

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Citation Number: 45

Abstract

Abstract: Separate Xe/03 and Xe/CzH4 mixtures were condensed on a CsI window at 50 K and then warmed to 80-100 K. Strong infrared absorptions due to the secondary ozonide and weaker bands at 409, 647, 727, 846, 927, 983, and 1214 cm-I replaced the ethylene and ozone absorptions. The latter new bands agree with earlier solid film and COz matrix studies and are assigned to the primary ozonide. Isotopic substitution (16* 1803, CHzCD2 ...