15N chemical shift tensors of uracil determined from 15N powder pattern and 15N-13C dipolar NMR spectroscopy

KL Anderson-Altmann, CG Phung…

Index: Anderson-Altmann, Karen L.; Phung, Cu G.; Mavromoustakos, Stylianos; Zheng, Zhiwen; Facelli, Julio C.; et al. Journal of Physical Chemistry, 1995 , vol. 99, # 26 p. 10454 - 10458

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Citation Number: 49

Abstract

The" N chemical shift tensors of uracil are reported using I5N powder pattem techniques. The principal values of the I5N uracil tensors are obtained from the spectra of [l-'5N] uracil and [3-'jN] uracil, and the tensor orientations are determined from the spectrum of [1, 3-'5N2, 2-'3C]~ ra~ i1 by including the effects of the direct dipolar interaction in the spectral fitting routine. Ambiguities in the orientational assignments, which arise from the axial symmetry ...