Advanced synthesis & catalysis

Chiral Bis (N??sulfonylamino) phosphine??and TADDOL??Phosphite??Oxazoline Ligands: Synthesis and Application in Asymmetric Catalysis

R Hilgraf, A Pfaltz

Index: Advanced Synthesis and Catalysis, , vol. 347, # 1 p. 61 - 77

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Citation Number: 100

Abstract

... Attempts to synthesize the 2,4,6-trimethylbenzyl de- rivative by the same route failed because the two or- tho-methyl groups ... Synthesis of methylated TADDAMIN ... in high regio- and enantioselectivity for the 1,3-dimethylallyl acetate (97 : 3, 94% ee).[14] All synthesized ligands ...