Synthesis, magnetism, 1 H NMR and redox activity of dicopper (II) complexes having a discrete {Cu 2 (µ-phenoxide) 2} 2+ unit supported by a non-macrocyclic ligand …

R Gupta, S Mukherjee, R Mukherjee

Index: Gupta, Rajeev; Mukherjee, Sumitra; Mukherjee, Rabindranath Journal of the Chemical Society - Dalton Transactions, 1999 , # 22 p. 4025 - 4030

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Abstract

Reaction between 4-methyl-2, 6-bis (pyrazol-1-ylmethyl) phenol (HL) or its 3, 5- dimethylpyrazole derivative (HL′[]) and Cu (ClO)· 6HO afforded [Cu (L/L′[])(OClO)] 1 and 2. Complex 1 has been structurally characterized showing that each copper () centre is ...