Polyhalogeno-allenes and-acetylenes. Part XIII [1]. Dechlorination of 1, 2, 2, 3-tetrachloro-1, 1, 3, 3-tetrafluoropropane as a route to tetrafluoroallene

…, WD Davies, RN Haszeldine, GR Lomax…

Index: Banks, R. E.; Davies, W. D.; Haszeldine, R. N.; Lomax, G. R.; Taylor, D. R. Journal of Fluorine Chemistry, 1980 , vol. 15, p. 79 - 82

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Abstract

During their pioneering work on the synthesis of tetrafluoroallene c2, jl t which established the'bromo routes' subsequently developed further in these laboratories c4, g, jacobs and Bauer tried unsuccessfully to effect exhaustive dechlorination of 1, 2, 2, 3-tetrachloro-l, l, j,~- tetrafluoropropane (CF ClCCl SF 2 2 $1) C3]* 7 ie-exszination of this method, using starting material obtained by treatment. of commercial c-dichlorotetrafluoroacetone with ...