e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Ungewöhnlich koordinierte Phosphorverbindungen: XXIV. Methylidinphosphan (HC P), ein neuer Cycloadditionspartner für 1, 3-Dipole
EPO Fuchs, M Hermesdorf, W Schnurr, W Rösch…
Index: Fuchs, E. P. O.; Hermesdorf, M.; Schnurr, W.; Roesch, W.; Heydt, H.; Regitz, M. Journal of Organometallic Chemistry, 1988 , vol. 338, p. 329 - 340
Abstract Methylidynephosphane (2) is generated under flash pyrolytic conditions by cleavage of isobutene from the phosphaalkyne (1) or by elimination of hydrogen chloride from dichloromethylphosphine (3). It undergoes [3+ 2]-cycloaddition reactions with stable dipoles eq. diazo compounds (2+ 4a, b→ 5a, b), methyl azide (2+ 7→ 8), benzonitriloxide (2+ 10→ 12, 1: 2-adduct) and 3-methyl-2, 4-diphenyl-1, 3-oxazolium-5-olate (2+ 13→ 15) ...
[Rregitz, Manfred; Roesh, Wolfgang; Allspach, Thomas; Annen, Ulrich; Blatter, Karsten; et al. Phosphorus and Sulfur and the Related Elements, 1987 , vol. 30, p. 479 - 482]
