The Journal of Organic Chemistry

Chemistry of aliphatic disulfides. XVII. Alkoxide cleavage of 3, 6-dibenzoyl-1, 8-diphenyl-4, 5-dithia-1, 8-octanedione

RG Hiskey, AJ Dennis

Index: Hiskey,R.G.; Dennis,A.J. Journal of Organic Chemistry, 1968 , vol. 33, p. 2734 - 2738

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Citation Number: 3

Abstract

Treatment of 3, 6-dibenzoyl-l, 8-diphenyl-4, 5dithiat-l, &octanedione (11) with potassium ethoxide in ethanol provides 3, 5dibenzoyl-l, 7diphenyl4thia-l, 7-heptanedione (IV) and potassium lI4diphenyl-2-butene-l, 4-dione-2-mercaptide (VII) as the major products. A