Substitution of aryl halides by thiolate anions

SD Pastor, JD Spivack, DW Hughes

Index: Pastor, Stephen D.; Spivack, John D.; Hughes, David W. Phosphorus and Sulfur and the Related Elements, 1984 , vol. 21, p. 39 - 46

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Citation Number: 3

Abstract

Abstract The reaction of 2.5-di-and 2, 3, 5, 6-tetrachloroterephthalate esters with both alkyl and arylmercaptides in triglyme solvent at room temperature gave the corresponding di-and tetra-substituted alkylthio-and arylthio-substituted terephthalate esters. Similarly, the reaction of both 2, 5-di-and 2, 3, 5, 6-tetrachloroterephthalate thioesters with potassium n- octylmercaptide, 2a, in triglyme gave the bis-and tetrakis (n-octylthio) terephthalate ...