Synthesis, crystal structure and luminescence properties of homodinuclear lanthanide complexes with a new tetrapodal thenylsalicylamide ligand

…, L Wang, MM Zhao, GQ Cheng, XR Wang…

Index: Song, Xue-Qin; Wang, Li; Zhao, Meng-Meng; Cheng, Guo-Quang; Wang, Xiao-Run; Peng, Yun-Qiao Inorganica Chimica Acta, 2013 , vol. 402, p. 156 - 164

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Citation Number: 9

Abstract

Five new homodinuclear lanthanide (III) complexes with a new tetrapodal thenylsalicylamide ligand (L), of formulae [Nd2L2 (NO3) 6 (CH3OH) 2]· 2H2O· 2CH3OH (1), and [Ln2L2 (NO3) 6 (CH3OH) 2]· 4CH3OH, Ln= Sm (2), Eu (3), Gd (4), Tb (5)) have been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and molar conductance analysis. The two arms of L ligand arranged in a complementary head ...