Reaction of [P3N3Cl4 (NH2) 2] with [HN (POCl2) 2]; The crystal structure of the phosphazenium salt [P3N3HCl4 (NH2) 2]+[N (POCl2) 2]−

…, A Mareček, Z Žák, P Pastera

Index: Alberti, M.; Marecek, A.; Zak, Z.; Pastera, P. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1995 , vol. 621, p. 1771 - 1774

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Citation Number: 2

Abstract

Abstract The reaction of diaminotetrachloro-cyclotriphosphazene with tetrachloride of μ- imino-diphosphoric acid leads to the formation of the salt-like compound [P 3 N 3 HCl 4 (NH 2) 2]+[N (POCl 2) 2]− which identity was unambiguously established by means of X-ray structure analysis. The structure is composed of [P 3 N 3 HCl 4 (NH 2) 2]+ cations and [N (POCl 2) 2]− anions joined by a system of H-bonds. As in other phosphazenium salts, the ...