Diversity in Complexation of [RhI (cod)]+ and [IrI (cod)]+ by Pyridine??Amine??Pyrrole Ligands

…, RJ Kicken, NFA Suos, MPJ Donners…

Index: De Bruin, Bas; Kicken, Reinout J. N. A. M.; Suos, Nicolaas F. A.; Donners, Maurice P. J.; Den Reijer, Carolien J.; Sandee, Albertus J.; De Gelder, Rene; Smits, Jan M. M.; Gal, Anton W.; Spek, Anton L. European Journal of Inorganic Chemistry, 1999 , # 9 p. 1581 - 1592

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Abstract

Abstract Complexation of [Rh I (cod)]+ and [Ir I (cod)]+ by the new pyridine-amine-pyrrole ligands Py–CH 2–N (R)–CH 2–Pyr–H (HL R; R= H, Bzl, Bu) and the corresponding pyridine- amine-pyrrolate ligands [Py–CH 2–N (R)–CH 2–Pyr]−(LR−; R= H, Bzl, Bu, CH 2 Py) has been investigated. The neutral ligands HL R (R= H, Bu, Bzl) give [(HL R) MI (cod)]+(M= Rh, Ir) in which HL R acts as a didentate ligand via the pyridine nitrogen (N Py) and the amine ...