Oxygen Glycosides from the Hilbert-Johnson Pyrimidine Nucleoside Synthesis1

P Newmark, I Goodman

Index: Newmark; Goodman Journal of the American Chemical Society, 1957 , vol. 79, p. 6446,6449

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Citation Number: 14

Abstract

Synthesis of the nucleosides of 6-methyluracil (I), 6-methyl-2-thiouracil (11), 2-thiouracil (111) and barbituric acid (IV) was attempted by means of the Hilbert and Johnson pyrimidine nucleoside synthesis. No nucleosides were obtained. Both a-and 0-isomers of the oxygen glucosides were isolated for I and 11, and as one of the by-products, 4-ethoxy-6-methyl-2 (1)- pyrimidone, all previously unreported. No condensation products were obtained for I11 or ...