Spectroscopic and electrochemical study of dinuclear and mononuclear copper complexes with the bidentate ligand of the 2, 2′-diquinoline series

…, AV Dolganov, AV Yakimanskii, MY Goikhman…

Index: Vatsadze; Dolganov; Yakimanskii; Goikhman; Podeshvo; Lyssenko; Maksimov; Magdesieva Russian Chemical Bulletin, 2010 , vol. 59, # 4 p. 724 - 732

Full Text: HTML

Citation Number: 4

Abstract

Abstract The newly synthesized complex (2) of copper (I) chloride with di-n-hexyl 2, 2′- biquinoline-4, 4′-dicarboxylate (L) was spectroscopically and electrochemically characterized. The X-ray diffraction study showed that the crystals of complex 2 consist of the dinuclear moieties [L 2 Cu 1 2 (μ-Cl) 2] containing Cu 2 (μ-Cl) 2 clusters. Spectrophotometric studies and ESI-mass spec-trometric measurements showed that after the dissolution of ...