The Journal of Organic Chemistry

Alkoxyl migration in displacement of a 5-trifluoromethanesulfonyloxy group from ribofuranosides

VK Iyer, JP Horwitz

Index: Iyer, Vaidyanathan K.; Horwitz, Jerome P. Journal of Organic Chemistry, 1982 , vol. 47, # 4 p. 644 - 649

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Citation Number: 16

Abstract

4a. n. 2 bn 3 in carbohydrate chemistry (inter alia) where the advantages of this exceptionally good leaving group have provided the basis of (i) a convenient synthesis of deoxyhalogeno sugar^,^(ii) highly stereoselective syntheses of 8-or a-glycosides and disacharide~+~ and (iii) the preparation of benzyl ether derivatives of appropriately protected carbohydrates. 6p7