Synthesis and Characterization of Novel Gold (III) Complexes of Asymmetrically Aryl??Substituted 1, 2??Dithiolene Ligands Featuring Potential??Controlled …

…, F Isaia, V Lippolis, A Mancini, A Pintus

Index: Ambrosio, Lucia; Aragoni, M. Carla; Arca, Massimiliano; Devillanova, Francesco A.; Hursthouse, Michael B.; Huth, Susanne L.; Isaia, Francesco; Lippolis, Vito; Mancini, Annalisa; Pintus, Anna Chemistry - An Asian Journal, 2010 , vol. 5, # 6 p. 1395 - 1406

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Citation Number: 10

Abstract

Abstract The tetrabutylammonium (TBA+) salts of square-planar monoanionic gold complexes of the unsymmetrically substituted Ar, H-edt 2− 1, 2-dithiolene ligands (Ar, H-edt 2−= arylethylene-1, 2-dithiolato; Ar= phenyl (1−), 2-naphthyl (2−), and 1-pyrenyl (3−)) were synthesized and characterized by spectroscopic and electrochemical methods and the corresponding neutral species (1, 2, and 3, respectively) were obtained in CH 2 Cl 2 ...