Sterically hindered free radicals. 14. Substituent-dependent stabilization of para-substituted triphenylmethyl radicals

WP Neumann, W Uzick…

Index: Neumann,W.P.; Uzick,W.; Zarkadis,A.K. Journal of the American Chemical Society, 1986 , vol. 108, p. 3762

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Citation Number: 63

Abstract

Abstract: This is a contribution to the problem of stabilization of free organic radicals by resonance in general and to the recent discussion of" captodative" stabilization in particular. It has been found that substituent-dependent relative stabilities of 4, 4'-disubstituted triarylmethyl radicals 1 can be sensitively determined by ESR spectroscopic measurement of the equilibria of dissociation of the quinonoid dimers 2 in 21 cases. Most of the ...