Journal of the American Chemical Society

Preparation of Organosilicon-and Organotin-substituted Boranes and their Oxidation to Organosilicon-and Organotin-substituted Alcohols1

D Seyferth

Index: Seyferth Journal of the American Chemical Society, 1959 , vol. 81, p. 1844,1846

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Citation Number: 1

Abstract

Oxidation of the silyl-boranes method.(Me8SiC2H4) 3B, in which the groupings MeaSiCH&HrB and MetSiCHMe-B occurred in about 2: l. molar ratio. ing the trimethylvinplsilane: NaBH, ratio gave products where this ratio was about 1: 1. using the method of Brown and Rao2 gave the corresponding alcohols in good yield.