Betylates. 4. The synthesis and preparative nucleophilic substitution reactions of alkyl S-[3] betylates

…, S Skonieczny, GA Poole

Index: King, James Frederick; Skonieczny, Stanislaw; Poole, Gary Allan Canadian Journal of Chemistry, 1983 , vol. 61, p. 235 - 243

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Citation Number: 13

Abstract

Alkyl S-[3] betylates (S, S-dialkyl-S-3 [(alkyloxy) sulfonyl] propylsulfonium salts), the first examples of S-betylates (sulfonioalkanesulfonic esters), have been synthesized by two routes, and their suitability as intermediates in the transformation of alcohols by nucleophilic substitution reactions examined. They have been found to react readily in stoichiometric phase transfer processes, including substrate-reagent ion-pair reactions, like their ...