Syntheses of Reductones. A New Method of Synthesizing 2-Acetoxy-1, 3-dicarbonyl Compounds

N Sugiyama, M Yamamoto, T Takano…

Index: Sugiyama,N. et al. Bulletin of the Chemical Society of Japan, 1967 , vol. 40, p. 2909 - 2913

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Citation Number: 7

Abstract

2-Acetoxy-l, 3-dicarbonyl compounds were synthesized by two methods, one consisting of the condensation of 1, 3-dicarbonyl compounds with an electrophilic reagent, followed by acetoxylation. By this method three new compounds, ethyl 5-phenyl-2-acetoxy-3- oxopentanoate (XVII), ethyl 5, 5-diphenyl-5-hydroxy-2-acetoxy-3-oxopentanoate (XVIII), and ethyl 2-acetoxy-3-oxoheptanoate (XIX), were obtained. The other method consisted of the ...